Methyl thiocyanate

Methyl thiocyanate

Names
Preferred IUPAC name Methyl thiocyanate
Other names Thiocyanic acid methyl ester;[1] Methylrhodanid; methylrhodanate; Methylthiokyanat; Thiocyanomethane; Methyl rhodanide; Methyl thiocyanate; thiocyanato-methan; methylsulfocyanate; Methylsalfocyanate[2]
Identifiers
CAS Number	556-64-9 Y
3D model (JSmol)	Interactive image
ChEBI	CHEBI:61112
ChemSpider	10695
ECHA InfoCard	100.008.305
EC Number	209-134-6
MeSH	C047435
PubChem CID	11168
UNII	55I23VY6IE Y
UN number	2929 1935
CompTox Dashboard (EPA)	DTXSID5060304
InChI InChI=1S/C2H3NS/c1-4-2-3/h1H3 Key: VYHVQEYOFIYNJP-UHFFFAOYSA-N
SMILES N#CSC
Properties
Chemical formula	C2H3NS
Molar mass	73.117
Appearance	Colourless liquid
Density	1.074 g/cm3
Melting point	−51 °C (−60 °F; 222 K)
Boiling point	132 °C (270 °F; 405 K) (101.3 kP)
Solubility in water	Slightly soluble[3]
Solubility in Diethyl ether	Miscible[3]
Structure
Molecular shape	bent C-S-CN
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H226, H301, H311, H315, H319, H330, H331, H335
Precautionary statements	P210, P233, P240, P241, P242, P243, P260, P261, P264, P270, P271, P280, P284, P301+P310, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P311, P312, P320, P321, P322, P330, P332+P313, P337+P313, P361, P362, P363, P370+P378, P403+P233, P403+P235, P405, P501
NFPA 704 (fire diamond)	3 3 0
Flash point	38 °C (100 °F; 311 K)[1]
Related compounds
Related compounds	Methyl isocyanate Methyl isothiocyanate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Methyl thiocyanate is an organic compound with the formula CH₃SCN. The simplest member of the organic thiocyanates, it is a colourless liquid with an onion-like odor. It is produced by the methylation of thiocyanate salts. The compound is a precursor to the more useful isomer methyl isothiocyanate (CH₃NCS).^[4]

Safety

The LD50 is 60 mg/kg (rats, oral).

It is listed as an extremely hazardous substance by the United States's Emergency Planning and Community Right-to-Know Act.^[5]

References